The first order rate constant for the decomposition of ethyl iodide by the reaction $C_{2}H_{5}I_{(g)} \rightarrow C_{2}H_{4(g)} + HI_{(g)}$ at $600 \ K$ is $1.60 \times 10^{-5} \ s^{-1}$. Its energy of activation is $209 \ kJ/mol$. Calculate the rate constant of the reaction at $700 \ K$.

Vedclass pdf generator app on play store
Vedclass iOS app on app store
(N/A) We use the Arrhenius equation in the form: $\log \frac{k_{2}}{k_{1}} = \frac{E_{a}}{2.303 \ R} \left[ \frac{T_{2} - T_{1}}{T_{1} T_{2}} \right]$
Given: $k_{1} = 1.60 \times 10^{-5} \ s^{-1}$,$T_{1} = 600 \ K$,$T_{2} = 700 \ K$,$E_{a} = 209000 \ J \ mol^{-1}$,$R = 8.314 \ J \ K^{-1} \ mol^{-1}$.
Substituting the values:
$\log \frac{k_{2}}{1.60 \times 10^{-5}} = \frac{209000}{2.303 \times 8.314} \left[ \frac{700 - 600}{600 \times 700} \right]$
$\log \frac{k_{2}}{1.60 \times 10^{-5}} = 10921.6 \times \frac{100}{420000} = 2.599$
$\frac{k_{2}}{1.60 \times 10^{-5}} = \text{antilog}(2.599) \approx 397.19$
$k_{2} = 397.19 \times 1.60 \times 10^{-5} \approx 6.36 \times 10^{-3} \ s^{-1}$

Explore More

Similar Questions

For an endothermic reaction,where $\Delta H$ represents the enthalpy of the reaction in $kJ/mol$,the minimum value for the energy of activation will be

The rate of gas phase chemical reactions generally increases rapidly with a rise in temperature. This is mainly because

Which statement is true with respect to a catalyst?

For a chemical reaction,if the temperature is increased from $25\,^{\circ}C$ to $55\,^{\circ}C$,the rate of reaction will change by a factor of (Assume $\mu = 3$).

The time required for $10 \%$ completion of a first order reaction at $298 \,K$ is equal to that required for its $25 \%$ completion at $308 \,K$. If the value of $A$ is $4 \times 10^{10} \,s^{-1}$,calculate $k$ at $318 \,K$ and $E_a$.

Difficult
View Solution

Vedclass Products

For Students

Vedclass Test Series

Mock tests in real JEE/NEET style with performance analysis. 5-day free trial.

Start Free Trial
For Teachers

Exam Paper Generator

Generate Set A/B/C/D exam papers from 7.5L+ questions in 2 minutes. 3 chapters free.

Try Free
For Institutes

Online Exam Module

Live online exams with unlimited students, 360° analytics & white-label branding.

See Demo