Which of the following statements is incorrect?

  • A
    The rate law for any reaction cannot be determined experimentally.
  • B
    Complex reactions have fractional order.
  • C
    Bimolecular reactions involve simultaneous collision between two species.
  • D
    Molecularity is only applicable for elementary reactions.

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The alkaline hydrolysis of an ester is a .......

Consider the following reactions:
$A$ $\rightarrow P_1; B$ $\rightarrow P_2; C$ $\rightarrow P_3; D$ $\rightarrow P_4$
The orders of the above reactions are $a, b, c,$ and $d,$ respectively. The following graph is obtained when $\log[\text{rate}]$ vs. $\log[\text{conc.}]$ are plotted:
Among the following,the correct sequence for the order of the reactions is:

Consider the following gas-phase reaction.
$2HI_{(g)} \longrightarrow H_{2(g)} + I_{2(g)}$
and the following experimental data obtained at $555 \ K$. What is the order of the reaction with respect to $HI_{(g)}$?
$[HI] \ (M)$ Rate $(M \ s^{-1})$
$0.0500$ $8.80 \times 10^{-10}$
$0.1000$ $3.52 \times 10^{-9}$
$0.1500$ $7.92 \times 10^{-9}$

Consider a reaction $aG + bH \rightarrow$ Products. When the concentration of both reactants $G$ and $H$ is doubled,the rate increases by $8$ times. However,when the concentration of $G$ is doubled keeping the concentration of $H$ fixed,the rate is doubled. The overall order of the reaction is:

For the reaction $2NO_{(g)} + O_{2_{(g)}} \rightarrow 2NO_{2_{(g)}}$,the volume of the reaction vessel is suddenly reduced to half of its original volume. If the reaction is first order with respect to $O_2$ and second order with respect to $NO$,the rate of the reaction will:

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