Which of the following statements are correct?
$A$. The $C-Cl$ bond in chlorobenzene is shorter than in chloromethane.
$B$. It is more difficult to replace chlorine from chlorobenzene than from benzyl chloride.
$C$. The $C-Cl$ bond in chlorobenzene has some double bond character.
$D$. Chlorobenzene on chlorination gives $m$-dichlorobenzene.

The decreasing order of reactivity of $m$-nitrobromobenzene $(I)$,$2,4,6$-trinitrobromobenzene $(II)$,$p$-nitrobromobenzene $(III)$,and $2,4$-dinitrobromobenzene $(IV)$ towards $OH^{-}$ ions is

$o$-Toluic acid on reaction with $Br_2 + Fe$ gives:

The reaction of compound $P$ with $CH_3MgBr$ (excess) in $(C_2H_5)_2O$ followed by addition of $H_2O$ gives $Q$. The compound $Q$ on treatment with $H_2SO_4$ at $0^{\circ}C$ gives $R$. The reaction of $R$ with $CH_3COCl$ in the presence of anhydrous $AlCl_3$ in $CH_2Cl_2$ followed by treatment with $H_2O$ produces compound $S$ [$Et$ in compound $P$ is ethyl group].
$(1)$ The product $S$ is
$(2)$ The reactions,$Q$ to $R$ and $R$ to $S$,are

$A$. Dehydration and Friedel-Crafts acylation	$B$. Aromatic sulfonation and Friedel-Crafts acylation
$C$. Friedel-Crafts alkylation,dehydration and Friedel-Crafts acylation	$D$. Friedel-Crafts alkylation and Friedel-Crafts acylation

Given the answer question $(1)$ and $(2)$

Which of the following does not give Friedel-Crafts reaction?

Which of the following substituents on benzene is ortho-para directing in electrophilic substitution and ortho-para directing in nucleophilic substitution?