Which of the following reactions will not give a primary amine?

$A$ colourless substance $'A'$ $(C_6H_7N)$ is sparingly soluble in water and gives a water-soluble compound $'B'$ on treating with mineral acid. On reacting with $CHCl_3$ and alcoholic potash,$'A'$ produces an obnoxious smell due to the formation of compound $'C'$. Reaction of $'A'$ with benzenesulphonyl chloride gives compound $'D'$ which is soluble in alkali. With $NaNO_2$ and $HCl$,$'A'$ forms compound $'E'$ which reacts with phenol in an alkaline medium to give an orange dye $'F'$. Identify compounds $'A'$ to $'F'$.

Number of structural isomers of $C_4H_{11}N$.

$p$-Toluidine reacts with benzene diazonium chloride to form a compound,which on boiling with $aq. H_2SO_4$ gives ........ products.

$9.3 \ g$ of pure aniline upon diazotisation followed by coupling with phenol gives an orange dye. The mass of orange dye produced (assume $100\%$ yield/conversion) is . . . . . $g$. (nearest integer)

The product $(A)$ of the reaction is: