Which of the following is correct ?

  • A

    molecularity of a reaction can be fractional

  • B

    Zero order reaction never stops

  • C

    A first order reaction must be homogeneous

  • D

    The rate constant of a reaction becomes equal to the pre-exponential factor when the absolute temperature is infinity.

Similar Questions

The rate law expression for the reaction $aA + bB \to P$ is rate $= K [A]^p [B]^q$ The order of the reaction is

For the reaction,

$2{N_2}{O_5}\, \to \,4N{O_2}\, + \,{O_2}$

the rate of reaction is

  • [AIIMS 2006]

Assuming the reaction

$2NO(g) + Cl_2(g) \longrightarrow 2NOCl(g)$

occurs in a single elementary step, we can say that

The experimental data for decomposition of $N _{2} O _{5}$

$\left[2 N _{2} O _{5} \rightarrow 4 NO _{2}+ O _{2}\right]$

in gas phase at $318 \,K$ are given below:

$t/s$ $0$ $400$ $800$ $1200$ $1600$ $2000$ $2400$ $2800$ $3200$
${10^2} \times \left[ {{N_2}{O_5}} \right]/mol\,\,{L^{ - 1}}$ $1.63$ $1.36$ $1.14$ $0.93$ $0.78$ $0.64$ $0.53$ $0.43$ $0.35$

$(i)$ Plot $\left[ N _{2} O _{5}\right]$ against $t$

$(ii)$ Find the half-life period for the reaction.

$(iii)$ Draw a graph between $\log \left[ N _{2} O _{5}\right]$ and $t$

$(iv)$ What is the rate law $?$

$(v)$ Calculate the rate constant.

$(vi)$ Calculate the half-life period from $k$ and compare it with $(ii)$.

The reaction $2 A + B _{2} \rightarrow 2 AB$ is an elementary reaction.

For a certain quantity of reactants, if the volume of the reaction vessel is reduced by a factor of $3,$ the rate of the reaction increases by a factor of $.....$. (Round off to the Nearest Integer).

  • [JEE MAIN 2021]