Which of the following is correct ?
molecularity of a reaction can be fractional
Zero order reaction never stops
A first order reaction must be homogeneous
The rate constant of a reaction becomes equal to the pre-exponential factor when the absolute temperature is infinity.
The rate law expression for the reaction $aA + bB \to P$ is rate $= K [A]^p [B]^q$ The order of the reaction is
For the reaction,
$2{N_2}{O_5}\, \to \,4N{O_2}\, + \,{O_2}$
the rate of reaction is
Assuming the reaction
$2NO(g) + Cl_2(g) \longrightarrow 2NOCl(g)$
occurs in a single elementary step, we can say that
The experimental data for decomposition of $N _{2} O _{5}$
$\left[2 N _{2} O _{5} \rightarrow 4 NO _{2}+ O _{2}\right]$
in gas phase at $318 \,K$ are given below:
$t/s$ | $0$ | $400$ | $800$ | $1200$ | $1600$ | $2000$ | $2400$ | $2800$ | $3200$ |
${10^2} \times \left[ {{N_2}{O_5}} \right]/mol\,\,{L^{ - 1}}$ | $1.63$ | $1.36$ | $1.14$ | $0.93$ | $0.78$ | $0.64$ | $0.53$ | $0.43$ | $0.35$ |
$(i)$ Plot $\left[ N _{2} O _{5}\right]$ against $t$
$(ii)$ Find the half-life period for the reaction.
$(iii)$ Draw a graph between $\log \left[ N _{2} O _{5}\right]$ and $t$
$(iv)$ What is the rate law $?$
$(v)$ Calculate the rate constant.
$(vi)$ Calculate the half-life period from $k$ and compare it with $(ii)$.
The reaction $2 A + B _{2} \rightarrow 2 AB$ is an elementary reaction.
For a certain quantity of reactants, if the volume of the reaction vessel is reduced by a factor of $3,$ the rate of the reaction increases by a factor of $.....$. (Round off to the Nearest Integer).