Which among the following pairs is not an acidic buffer?

The buffer system which helps to maintain the $pH$ of blood between $7.26$ to $7.42$ is:

In which of the following combinations is buffer action expected?
$(a)$ $NH_4OH + NH_4Cl$
$(b)$ $HCl + NaCl$
$(c)$ $NH_4OH + HCl$ in $2:1$ mole ratio
Select the correct answer using the code given below.

$20 \ mL$ of $0.1 \ M$ acetic acid is mixed with $50 \ mL$ of potassium acetate. $K_a$ of acetic acid $= 1.8 \times 10^{-5}$ at $27^{\circ} C$. Calculate the concentration of potassium acetate if the $pH$ of the mixture is $4.8$. (in $M$)

$A$ solution is prepared by mixing $0.01 \ mol$ each of $H_2CO_3$,$NaHCO_3$,$Na_2CO_3$,and $NaOH$ in $100 \ mL$ of water. The $pH$ of the resulting solution is. . . . . . .
[Given : $pK_{a1}$ and $pK_{a2}$ of $H_2CO_3$ are $6.37$ and $10.32$,respectively; $\log 2=0.30$ ]

$A$ certain buffer solution contains equal concentrations of $X^{-}$ and $HX$. The $K_a$ for $HX$ is $10^{-8}$. The $pH$ of the buffer is