What is mean free path? Derive the equation for the mean free path.

Vedclass pdf generator app on play store
Vedclass iOS app on app store
(N/A) The average distance traveled by gas molecules between two successive collisions is called the mean free path.
The calculation of the mean free path is based on two hypotheses:
$(1)$ Gas molecules are rigid spheres of diameter '$d$'.
$(2)$ Molecules other than the one in motion are considered stationary.
Let the diameter of a gas molecule be $d$ and the average speed of one molecule be $\langle v \rangle$.
Let this molecule collide with any other molecule that comes within a distance $d$ between their centers.
It sweeps a volume $\pi d^{2} \langle v \rangle \Delta t$ in a time interval $\Delta t$.
If $n$ is the number of molecules per unit volume,the molecule undergoes $n \pi d^{2} \langle v \rangle \Delta t$ collisions in the time interval $\Delta t$.
Thus,the rate of collision is $n \pi d^{2} \langle v \rangle$.
The time interval between two successive collisions is:
$\tau = \frac{1}{n \pi \langle v \rangle d^{2}}$
The average distance between two successive collisions is called the mean free path,denoted by $\bar{l}$.
$\therefore \bar{l} = \langle v \rangle \tau$
$\therefore \bar{l} = \frac{1}{n \pi d^{2}}$

Explore More

Similar Questions

$A$ fixed amount of nitrogen gas ($1$ mole) is taken and subjected to pressure and temperature variations. The experiment is performed at high pressures and various temperatures. The results obtained are shown in the figure. The correct variation of $PV/RT$ with $P$ for nitrogen gas at high temperatures will be exhibited by:

According to the Kinetic Theory of Gases,which of the following statements is correct?

An ideal gas is enclosed in a cylinder at a pressure of $2 \, atm$ and a temperature of $300 \, K$. The mean time between two successive collisions is $6 \times 10^{-8} \, s$. If the pressure is doubled and the temperature is increased to $500 \, K$,the mean time between two successive collisions will be close to:

$A$ container is divided into two equal parts $I$ and $II$ by a partition with a small hole of diameter $d$. The two parts are filled with the same ideal gas,but held at temperatures $T_{I} = 150 \, K$ and $T_{II} = 300 \, K$ by connecting them to heat reservoirs. Let $\lambda_{I}$ and $\lambda_{II}$ be the mean free paths of the gas particles in the two parts,such that $d \gg \lambda_{I}$ and $d \gg \lambda_{II}$. Then,the ratio $\lambda_{I} / \lambda_{II}$ is close to:

Write the equation for the mean free path of gas molecules.

Vedclass Products

For Students

Vedclass Test Series

Mock tests in real JEE/NEET style with performance analysis. 5-day free trial.

Start Free Trial
For Teachers

Exam Paper Generator

Generate Set A/B/C/D exam papers from 7.5L+ questions in 2 minutes. 3 chapters free.

Try Free
For Institutes

Online Exam Module

Live online exams with unlimited students, 360° analytics & white-label branding.

See Demo