What is enthalpy of atomisation? Explain. $OR$ Write a note on enthalpy of atomisation.

Vedclass pdf generator app on play store
Vedclass iOS app on app store
(N/A) The energy required to form $1 \ mol$ of gaseous atoms from its element in its standard state is called standard enthalpy of atomisation $(\Delta_a H^{\ominus})$.
The transition elements have high enthalpies of atomisation because of the presence of strong inter-atomic interactions (strong metallic bonds) between the atoms.
The enthalpy of atomisation generally increases with the increase in the number of unpaired electrons,which results in the formation of stronger metallic bonds.
The elements of $4d$ and $5d$ series have greater enthalpy of atomisation than the corresponding elements of the first transition series ($3d$ series),which results in much more metal-metal bonding in compounds of the heavy transition elements.
Trends in enthalpies of atomisation of transition elements:
In the first transition series,$Zn$ has the minimum enthalpy of atomisation because of the absence of unpaired electrons in its $d$-orbitals ($3d^{10} 4s^2$ configuration).

Explore More

Similar Questions

Why is the highest oxidation state of a metal exhibited in its oxide or fluoride only?

Choose the correct statement. $Fe^{3+}$ ion is more stable than $Fe^{2+}$ ion because

Which of the following has the maximum number of unpaired electrons?

The general electronic configuration of transition elements is

Which of the following statements is correct?

Difficult
View Solution

Vedclass Products

For Students

Vedclass Test Series

Mock tests in real JEE/NEET style with performance analysis. 5-day free trial.

Start Free Trial
For Teachers

Exam Paper Generator

Generate Set A/B/C/D exam papers from 7.5L+ questions in 2 minutes. 3 chapters free.

Try Free
For Institutes

Online Exam Module

Live online exams with unlimited students, 360° analytics & white-label branding.

See Demo