What is crystal field splitting energy? How does the magnitude of $\Delta_{o}$ decide the actual configuration of $d$-orbitals in a coordination entity?

Vedclass pdf generator app on play store
Vedclass iOS app on app store
(N/A) The degenerate $d$-orbitals (in a spherical field environment) split into two levels,i.e.,$e_{g}$ and $t_{2g}$,in the presence of ligands. The splitting of the degenerate levels due to the presence of ligands is called the crystal-field splitting,while the energy difference between the two levels ($e_{g}$ and $t_{2g}$) is called the crystal-field splitting energy. It is denoted by $\Delta_{o}$.
After the orbitals have split,the filling of the electrons takes place. After $1$ electron (each) has been filled in the three $t_{2g}$ orbitals,the filling of the fourth electron takes place in two ways. It can enter the $e_{g}$ orbital (giving rise to $t_{2g}^{3} e_{g}^{1}$ electronic configuration) or the pairing of the electrons can take place in the $t_{2g}$ orbitals (giving rise to $t_{2g}^{4} e_{g}^{0}$ electronic configuration). If the $\Delta_{o}$ value of a ligand is less than the pairing energy $(P)$,then the electrons enter the $e_{g}$ orbital. On the other hand,if the $\Delta_{o}$ value of a ligand is more than the pairing energy $(P)$,then the electrons enter the $t_{2g}$ orbital.

Explore More

Similar Questions

How is the $t_{2g}^4 e_g^0$ configuration possible for a $d^4$ ion during crystal field splitting in an octahedral complex?

Complexes with $CN^{-}$ ligands are generally .......

The number of unpaired electrons in the complex ion $[CoF_6]^{3-}$ is (Atomic number of $Co = 27$).

Which among the following is a correct order of increasing field strength of ligands?

The crystal field stabilisation energy $(CFSE)$ and the spin-only magnetic moment in Bohr Magneton $(BM)$ for the complex $K_3[Fe(CN)_6]$ are,respectively

Vedclass Products

For Students

Vedclass Test Series

Mock tests in real JEE/NEET style with performance analysis. 5-day free trial.

Start Free Trial
For Teachers

Exam Paper Generator

Generate Set A/B/C/D exam papers from 7.5L+ questions in 2 minutes. 3 chapters free.

Try Free
For Institutes

Online Exam Module

Live online exams with unlimited students, 360° analytics & white-label branding.

See Demo