What is boiling point? What is freezing point?

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(N/A) $1$. Boiling point: The boiling point of a liquid is the temperature at which its vapor pressure becomes equal to the atmospheric pressure $(1.013 \ bar)$.
$2$. Freezing point: The freezing point of a substance is the temperature at which the vapor pressure of the substance in its liquid phase is equal to the vapor pressure of the substance in its solid phase.

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Choose the correct answer from the options given below $:$

Calculate the osmotic pressure in $atm$ at $0\,^oC$ of a $0.18\, m$ aqueous solution of $KCl$ which has a freezing point of $-0.68\,^oC$. Assume the volume of the solution is equal to the volume of pure water. $(K_f = 1.86\,^oC\, m^{-1})$

$PbCl_2$ is dissolved in water to make its saturated solution. What will be the freezing point of this solution?
Given: $K_f (H_2O) = 2 \ K \ kg \ mol^{-1}$,$K_{sp} (PbCl_2) = 4 \times 10^{-6}$
(Assume molarity to be equal to molality) $..... ^oC$

An aqueous solution of urea (molar mass $= 60 \ g \ mol^{-1}$) boils at $100.18^o C$ at atmospheric pressure. If $K_f = 1.86 \ K \ kg \ mol^{-1}$ and $K_b = 0.512 \ K \ kg \ mol^{-1}$ for water,then the freezing point of the solution is equal to ..... $^o C$.

An amalgam of mercury with sodium is an example of:

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