What are the enthalpies of $\sigma$-bond and $\pi$-bonds in an alkene?

  • A
    $397 \ kJ \ mol^{-1}$ and $284 \ kJ \ mol^{-1}$
  • B
    $284 \ kJ \ mol^{-1}$ and $397 \ kJ \ mol^{-1}$
  • C
    $450 \ kJ \ mol^{-1}$ and $300 \ kJ \ mol^{-1}$
  • D
    $300 \ kJ \ mol^{-1}$ and $450 \ kJ \ mol^{-1}$

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$Isobutene + HBr \xrightarrow{\text{Peroxide}} \text{Product}$ is:

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$CH_3-CH=CH-C_2H_5 + Br_2 \rightarrow ?$

Which of the following intermediates is formed to produce the major product in the addition of $HBr$ to propene in the presence of peroxide?

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