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Match the items of column $-I$ with the items of column $-II$.
Column $-I$ Column $-II$
$(A)$ Methanol $(1)$ Conversion of phenol to $o-$hydroxybenzoic acid
$(B)$ Kolbe's reaction $(2)$ Ethyl alcohol
$(C)$ Williamson's synthesis $(3)$ Conversion of phenol to salicylaldehyde
$(D)$ Conversion of $2^o-$ alcohol to ketone $(4)$ Wood spirit
$(E)$ Reimer-Tiemann reaction $(5)$ Heated copper at $573 \ K$
$(F)$ Fermentation $(6)$ Reaction of alkyl halide with sodium alkoxide

When phenol is treated with $CHCl_3$ and $NaOH$ followed by acidification,salicylaldehyde is produced. Which of the following intermediates is involved in the above reaction?

Match the following:
Column-$I$: Compound / Reagent Column-$II$: Other name / Chemical / Process
$A$. Methanol $I$. Lucas reagent
$B$. $ZnCl_2$ / Conc. $HCl$ $II$. Baeyer's reagent
$C$. Rectified spirit $III$. Wood spirit
$D$. Dil. $KMnO_4$ $IV$. $95 \% C_2H_5OH$
- $V$. $75 \% C_2H_5OH$
- $VI$. $90 \% C_3H_7OH$

The correct match is:

Give equations of the following reactions:
$(i)$ Oxidation of propan$-1-$ol with alkaline $KMnO_4$ solution.
$(ii)$ Bromine in $CS_2$ with phenol.
$(iii)$ Dilute $HNO_3$ with phenol.
$(iv)$ Treating phenol with chloroform in presence of aqueous $NaOH$.

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If the starting material is $1-$methyl$-1,2-$epoxycyclopentane,determine which compound correctly represents the product of its reaction with sodium methoxide in methanol.

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