The reaction of hydrogen and iodine monochloride is given as :
$H_{2(g)} + 2ICl_{(g)} \rightarrow 2HCl_{(g)} + I_{2(g)}$
This reaction is of first order with respect to $H_{2(g)}$ and $ICl_{(g)}$. The following mechanisms were proposed:
Mechanism $A$ :
$H_{2(g)} + 2ICl_{(g)} \rightarrow 2HCl_{(g)} + I_{2(g)}$
Mechanism $B$ :
$H_{2(g)} + ICl_{(g)} \rightarrow HCl_{(g)} + HI_{(g)}$ ; (slow)
$HI_{(g)} + ICl_{(g)} \rightarrow HCl_{(g)} + I_{2(g)}$ ; (fast)
Which of the above mechanism$(s)$ can be consistent with the given information about the reaction?

  • A
    $A$ and $B$ both
  • B
    Neither $A$ nor $B$
  • C
    $A$ only
  • D
    $B$ only

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In a reaction between $A$ and $B$,the initial rate of reaction $(r_0)$ was measured for different initial concentrations of $A$ and $B$ as given below:
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