The reaction of aqueous $[Ni(H_2O)_6]^{2+}$ is performed by the addition of a bidentate ligand ethane-$1,2$-diamine $(en)$. Match the following:
$[Ni(H_2O)_6]^{2+} : en$ molar ratioColour of the product
$A. 1:1$$I. \text{Pale blue}$
$B. 1:2$$II. \text{Blue/Purple}$
$C. 1:3$$III. \text{Violet}$

The correct match is:

  • A
    $A-I, B-II, C-III$
  • B
    $A-II, B-III, C-IV$
  • C
    $A-III, B-I, C-II$
  • D
    $A-IV, B-I, C-III$

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$(c) \ K_4[Fe(CN)_6]$
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$CuSO_{4(aq)}$ $\xrightarrow{H_2S \uparrow} M \downarrow$ $\xrightarrow[\text{Excess}]{KCN} N + O$
Then final products $N$ and $O$ are respectively.

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The number of species having a square planar shape from the following is $........$.
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