Consider the following complexes:
$(a) \ Na_2[Fe(CN)_5NO]$
$(b) \ [Fe(H_2O)_5NO]SO_4$
$(c) \ K_4[Fe(CN)_6]$
Which of the following statements is wrong?

  • A
    $(a)$ is used in the detection of $S^{2-}$ ions.
  • B
    The complex part of each compound is octahedral.
  • C
    $(c)$ is used in the detection of $Fe^{3+}$ ions.
  • D
    The oxidation state $(O.S.)$ of $Fe$ in $(a)$ and $(b)$ is $+1$.

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Similar Questions

When potassium iodide is added to an aqueous solution of potassium ferricyanide,a reversible reaction is observed in which a complex $P$ is formed. In a strong acidic medium,the equilibrium shifts completely towards $P$. Addition of zinc chloride to $P$ in a slightly acidic medium results in a sparingly soluble complex $Q$.
$(1)$ The number of moles of potassium iodide required to produce two moles of $P$ is. . .
$(2)$ The number of zinc ions present in the molecular formula of $Q$ is. . . .
Give the answer for $(1)$ and $(2)$.

Match List-$I$ with List-$II$ and select the correct code:
List-$I$ List-$II$
$A$. Ziegler-Natta $i$. $Fe_4[Fe(CN)_6]_3$
$B$. Brown ring complex $ii$. $[Fe(H_2O)_5NO]SO_4$
$C$. Prussian Blue $iii$. $Al(C_2H_5)_3 + TiCl_4$
$D$. Turnbull Blue $iv$. $Fe_3[Fe(CN)_6]_2$

Correct code is:

Write down the $IUPAC$ name for each of the following complexes and indicate the oxidation state,electronic configuration,and coordination number. Also,give the stereochemistry and magnetic moment of the complex:
$(i)$ $K[Cr(H_2O)_2(C_2O_4)_2] \cdot 3H_2O$
$(ii)$ $[Co(NH_3)_5Cl]Cl_2$
$(iii)$ $CrCl_3(py)_3$
$(iv)$ $Cs[FeCl_4]$
$(v)$ $K_4[Mn(CN)_6]$

Difficult
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Match the following:
Column-$1$ (Reaction)Column-$2$ (Main product)
$A$. $4FeCl_3 + 3K_4[Fe(CN)_6] \rightarrow$$I$. $Fe_4[Fe(CN)_6]_3$
$B$. $ZnCl_2 + 4NaOH \rightarrow$$V$. $Na_2ZnO_2$
$C$. $2FeCl_3 + H_2S \rightarrow$$II$. $FeCl_2$

Three arrangements are shown for the complex $[CoBr_2(NH_3)_2(en)]^{\oplus}$. Which one is the wrong statement?

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