The ratio of volumes of $CH_3COOH$ $0.1 \ N$ to $CH_3COONa$ $0.1 \ N$ required to prepare a buffer solution of $pH$ $5.74$ is (Given,$pK_a$ of $CH_3COOH$ is $4.74$)

$2 \ g$ acetic acid and $3 \ g$ sodium acetate are present in $100 \ mL$ aqueous solution. What will be the $pH$ of the solution if the ionisation constant of acetic acid is $1.8 \times 10^{-5}$?

The dissociation constant of $HCN$ is $5 \times 10^{-10}$. The $pH$ of the solution prepared by mixing $1.5 \, mole$ of $HCN$ and $0.15 \, mole$ of $KCN$ in water and making up the total volume to $0.5 \, dm^3$ is (in $.302$)

In some solutions,the concentration of $H_3O^{+}$ remains constant even when small amounts of strong acid or strong base are added to them. These solutions are known as

Given below are two statements:
Statement $I$: $A$ buffer solution is the mixture of a salt and an acid or a base mixed in any particular quantities.
Statement $II$: Blood is a naturally occurring buffer solution whose $pH$ is maintained by $H_2CO_3 / HCO_3^{-}$ concentrations.
In the light of the above statements,choose the correct answer from the options given below.

In which of the following does a buffer solution play an important role?