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(D) To determine the number of species with a square pyramidal structure,we analyze the hybridization and geometry of each:$1$. $PF_{5}$: $sp^{3}d$ hy

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$3$

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(D) To determine the number of species with a square pyramidal structure,we analyze the hybridization and geometry of each:$1$. $PF_{5}$: $sp^{3}d$ hybridization,trigonal bipyramidal geometry.$2$. $BrF_{4}^{-}$: $sp^{3}d^{2}$ hybridization with $2$ lone pairs,square planar geometry.$3$. $IF_{5}$: $sp^{3}d^{2}$ hybridization with $1$ lone pair,square pyramidal geometry.$4$. $BrF_{5}$: $sp^{3}d^{2}$ hybridization with $1$ lone pair,square pyramidal geometry.$5$. $XeOF_{4}$: $sp^{3}d^{2}$ hybridization with $1$ lone pair,square pyramidal geometry.$6$. $ICl_{4}^{-}$: $sp^{3}d^{2}$ hybridization with $2$ lone pairs,square planar geometry.The species with a square pyramidal structure are $IF_{5}$,$BrF_{5}$,and $XeOF_{4}$.Therefore,the total number of such species is $3$.

The number of species from the following which have a square pyramidal structure is $PF_{5}$,$BrF_{4}^{-}$,$IF_{5}$,$BrF_{5}$,$XeOF_{4}$,$ICl_{4}^{-}$.

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