The molar heats of fusion and vaporisation of benzene are $10.9$ and $31.0 \ kJ \ mol^{-1}$ respectively. The changes in entropy for the solid $\rightarrow$ liquid and liquid $\rightarrow$ vapour transitions for benzene are $x$ and $y \ JK^{-1} \ mol^{-1}$,respectively. The value of $(y-x)$ (in $JK^{-1} \ mol^{-1}$) is (At $1 \ atm$,benzene melts at $5.5^{\circ} C$ and boils at $80^{\circ} C$).
- A$87.8$
- B$48.7$
- C$39.1$
- D$28.7$
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When $128 \, g$ of oxygen gas is heated from $0 \, ^oC$ to $100 \, ^oC$,the average values of $C_v$ and $C_p$ are $5 \, cal \, mol^{-1} \, K^{-1}$ and $7 \, cal \, mol^{-1} \, K^{-1}$ respectively. Find the values of $\Delta U$ and $\Delta H$.
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View SolutionGiven below are two statements:
Statement $I$: For an ideal gas,heat capacity at constant volume is always greater than the heat capacity at constant pressure.
Statement $II$: In a constant volume process,no work is produced and all the heat withdrawn goes into the chaotic motion and is reflected by a temperature increase of the ideal gas.
Statement $I$: For an ideal gas,heat capacity at constant volume is always greater than the heat capacity at constant pressure.
Statement $II$: In a constant volume process,no work is produced and all the heat withdrawn goes into the chaotic motion and is reflected by a temperature increase of the ideal gas.
The heat of reaction for $C_6H_{12}O_{6(s)} + 6O_{2(g)} \to 6CO_{2(g)} + 6H_2O_{(l)}$ at constant pressure is $-651 \, kcal$ at $17 \, ^oC$. Calculate the heat of reaction at constant volume at $17 \, ^oC$ in $kcal$.
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View SolutionThe enthalpy of sublimation of $I_{2(s)}$ is $57.3 \, kJ \, mol^{-1}$ and the enthalpy of fusion is $15.5 \, kJ \, mol^{-1}$. The enthalpy of vaporization of $I_2$ is ..................... $kJ \, mol^{-1}$. (in $.8$)
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View SolutionThe entropy change associated with the conversion of $1 \ kg$ of ice at $273 \ K$ to water vapours at $383 \ K$ is: (Specific heat of water liquid and water vapours are $4.2 \ kJ \ K^{-1} \ kg^{-1}$ and $2.0 \ kJ \ K^{-1} \ kg^{-1},$ heat of fusion and vaporisation of water are $334 \ kJ \ kg^{-1}$ and $2491 \ kJ \ kg^{-1},$ respectively) $(\ln \ 273 = 5.61, \ln \ 373 = 5.92, \ln \ 383 = 5.95)$
DifficultJEE MAIN 2019
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