One mole of an ideal monoatomic gas is heated in a process $PV^{5/2} = \text{constant}$. The amount of heat absorbed in the process for a $36 \ ^\circ C$ rise in temperature is (in $cal$):

  • A
    $60$
  • B
    $30$
  • C
    $108$
  • D
    $180$

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The standard enthalpies of formation of $1,3-butadiene(g)$,$CO_{2(g)}$,and $H_2O_{(l)}$ at $298 \ K$ are $-30$,$-94$,and $-68 \ kcal/mol$ respectively. If the magnitude of resonance enthalpies of $1,3-butadiene$ and $CO_2$ are $10$ and $20 \ kcal/mol$ respectively,the enthalpy of combustion of $1,3-butadiene(g)$ at $298 \ K$ is $........ \ kcal/mol$. (Enthalpy of vaporization of $H_2O_{(l)}$ at $298 \ K = 10 \ kcal/mol$)

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For the following combustion reaction occurring in an automobile: $2C_{8}H_{18(g)} + 25O_{2(g)} \to 16CO_{2(g)} + 18H_{2}O_{(g)}$,what are the signs of $\Delta H$,$\Delta S$,and $\Delta G$?

What is the value of $\Delta S_{\text{total}}$ for the following reaction at $300 \ K$:
$Fe_{2}O_{3(s)} + 3CO_{(g)} \longrightarrow 2Fe_{(s)} + 3CO_{2(g)}$
$\Delta H^{\circ} = -25 \ kJ, \Delta S^{\circ} = 15 \ J \ K^{-1}$ (in $J \ K^{-1}$)

Match the following processes with their corresponding entropy changes:
Process Entropy Change
$(a)$ Liquid to vapor conversion $(1)$ $\Delta S = 0$
$(b)$ Process not spontaneous at any temperature $(2)$ $\Delta S = (+)$
$(c)$ Reversible expansion of an ideal gas $(3)$ $\Delta S = (-)$

The enthalpy of vaporization of a liquid at $500 \, K$ and $1 \, atm$ pressure is $10 \, kcal \, mol^{-1}$. The change in internal energy $(\Delta U)$ for $3 \, moles$ of the liquid at the same temperature and pressure is ............ $kcal$.

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