The molar conductivity of $0.027 \ M$ methanoic acid is $40.42 \ S \ cm^2 \ mol^{-1}$. The value of dissociation constant of this acid is
(Given $\lambda_{H^{+}}^{\circ} = 349.6 \ S \ cm^2 \ mol^{-1}$ and $\lambda_{HCOO^{-}}^{\circ} = 54.6 \ S \ cm^2 \ mol^{-1}$)

  • A
    $1.5 \times 10^{-5}$
  • B
    $6.0 \times 10^{-5}$
  • C
    $4.5 \times 10^{-4}$
  • D
    $3.0 \times 10^{-4}$

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The conductivity of $0.01 \ M$ aqueous acetic acid measured with a conductivity cell of cell constant $0.5 \ cm^{-1}$ at $298 \ K$ is $3.12 \times 10^{-4} \ S$. If the limiting molar conductivities of $H^{+}$ and $CH_3COO^{-}$ at the same temperature are $349$ and $41 \ S \ cm^2 \ mol^{-1}$ respectively,the dissociation constant of acetic acid is

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