The mechanism of the reaction $2NO_2 + F_2 \to 2NO_2F$ is
$(i)\,\,N{O_2}\,\xrightarrow{{slow}}\,NO + O$
$(ii)\,\,{F_2} + O + NO\,\xrightarrow{{fast}}\,N{O_2}F + F$
$(iii)\,\,F + N{O_2}\,\xrightarrow{{fast}}\,N{O_2}F$
Select the correct one
the reaction is of $3^{rd}$ order
the molecularity of the reaction is sum of molecularities of all steps
reaction is zero order w.r.t. $F_2$
half life of reaction depends upon initial conc. of $NO_2$
In a reaction, $2X \to Y$ , the concentration of $X$ decreases from $0.50\, M$ to $0.38\, M$ in $10\, min$ . what is the rate of reaction in $Ms^{-1}$ during the interval ?
For the following reaction scheme (homogeneous), the rate constant has units
$A+B\xrightarrow{K}C$:
The reaction $CH _{3} COF + H _{2} O \quad \rightleftharpoons CH _{3} COOH + HF$
Condition $I$ $:$ $\left[ H _{2} O \right]_{0}=1.00 \,M$
$\left[ CH _{3} COF \right]_{0}=0.01 \,M$
Condition $II$ $:$ $\left[ H _{2} O \right]_{0}=0.02 \,M$
$\left[ CH _{3} COF \right]_{0}=0.80 \,M$
Condition - $I$ | Condition - $II$ | ||
Time $min$ |
$\left[ CH _{3} COF \right]$ $M$ |
Time $min$ |
$\left[ H _{2} O \right] \,M$ |
$0$ | $0.01000$ | $0$ | $0.0200$ |
$10$ | $0.00867$ | $10$ | $0.0176$ |
$20$ | $0.00735$ | $20$ | $0.0156$ |
$40$ | $0.00540$ | $40$ | $0.0122$ |
Determine the order of reaction and calculate rate constant.
Write differential rate expression of following reaction and give its order of reaction :
$H _{2} O _{2}+ I ^{-} \rightarrow H _{2} O + IO ^{-}$
$H _{2} O _{2}+ IO ^{-} \rightarrow H _{2} O + I ^{-}+ O _{2}$
For a reaction $A+ B\to $ Products, the rate law is - Rate $=$ $k\,[A]\, [B]^{\frac {3}{2}}$ . Can the reaction be an elementary reaction ? Explain.