The intermediate during the addition of HCl t | vedclass

Name: Exam Paper Generator | JEE NEET Paper Generator | Vedclass
Brand: Vedclass
Rating: 5 (35 reviews)

Question

(B) The addition of $HCl$ to propene follows Markovnikov's rule,even in the presence of peroxide.Peroxide effect (Kharasch effect) is only applicable

Vedclass · Accepted Answer

$CH_3-CH^{+}-CH_3$

Vedclass · Answer

(B) The addition of $HCl$ to propene follows Markovnikov's rule,even in the presence of peroxide.Peroxide effect (Kharasch effect) is only applicable to $HBr$ and not to $HCl$ or $HI$.In the reaction,the electrophile $H^+$ attacks the double bond to form the more stable secondary carbocation,$CH_3-CH^{+}-CH_3$,as the reaction intermediate.Therefore,the correct intermediate is $CH_3-CH^{+}-CH_3$.

The intermediate during the addition of $HCl$ to propene in the presence of peroxide is

Similar Questions

Which of the following is the most stable alkene?

$A \xleftarrow[\Delta]{Cu} CH_3CH_2OH \xrightarrow[\Delta]{Al_2O_3} B$. $A$ and $B$ respectively are

The reaction of $HBr$ with $CH_3-C(CH_3)=CH_2$ in the presence of peroxide will give:

$A$ hydrocarbon '$X$' with formula $C_6H_8$ uses two moles of $H_2$ on catalytic hydrogenation of its one mole. On ozonolysis,'$X$' yields two moles of methane dicarbaldehyde (malonaldehyde). The hydrocarbon '$X$' is :

Which alkene is most stable?

Vedclass Test Series

Exam Paper Generator

Online Exam Module