The half life for the decomposition of gaseous compound $A$ is $240\,s$ when the gaseous pressure was $500\,Torr$ initially. When the pressure was $250\,Torr$, the half life was found to be $4.0\,min$. The order of the reaction is....... (Nearest integer)
$4$
$3$
$2$
$1$
Reaction : $2Br^{-} + H_2O_2 + 2H^{+} \to Br_2 + 2H_2O$
take place in two steps :
$(a)$ $Br^{-} + H^{+} + H_2O_2 \xrightarrow{{slow}} HOBr + H_2O$
$(b)$ $HOBr + Br^{-} + H^{+} \xrightarrow{{fast}} H_2O + Br_2$
The order of the reaction is
For which order reaction a straight line is obtained along with $x\,-$ axis by plotting a graph between half life $({t_{1/2}})$ and initial concentration $ 'a'$
Calculate the order of the reaction in $A$ and $B$
$A$ $(mol/l)$ |
$B$ $(mol/l)$ |
Rate |
$0.05$ | $0.05$ | $1.2\times 10^{-3}$ |
$0.10$ | $0.05$ | $2.4\times 10^{-3}$ |
$0.05$ | $0.10$ | $1.2\times 10^{-3}$ |
The unit of rate constant for a zero order reaction is
The half-life of $2 $ sample are $0.1 $ and $ 0.4 $ seconds. Their respective concentration are $200 $ and $ 50 $ respectively. What is the order of the reaction