Medium
The following results have been obtained during the kinetic studies of the reaction: $2 \ NO + 2 \ H_2 \longrightarrow N_2 + 2 \ H_2O$
Expt $\frac{-d[NO]}{dt} \ (mol \ L^{-1} \ s^{-1})$ $[NO] \ (mol \ L^{-1})$ $[H_2] \ (mol \ L^{-1})$ $1$ $4.8 \times 10^{-5}$ $1 \times 10^{-2}$ $1 \times 10^{-3}$ $2$ $43.2 \times 10^{-5}$ $3 \times 10^{-2}$ $1 \times 10^{-3}$ $3$ $86.4 \times 10^{-5}$ $3 \times 10^{-2}$ $2 \times 10^{-3}$
| Expt | $\frac{-d[NO]}{dt} \ (mol \ L^{-1} \ s^{-1})$ | $[NO] \ (mol \ L^{-1})$ | $[H_2] \ (mol \ L^{-1})$ |
| $1$ | $4.8 \times 10^{-5}$ | $1 \times 10^{-2}$ | $1 \times 10^{-3}$ |
| $2$ | $43.2 \times 10^{-5}$ | $3 \times 10^{-2}$ | $1 \times 10^{-3}$ |
| $3$ | $86.4 \times 10^{-5}$ | $3 \times 10^{-2}$ | $2 \times 10^{-3}$ |
- A$\frac{-d[NO]}{dt} = k[NO]^2[H_2]$
- B$\frac{-d[NO]}{dt} = k[NO]^2[H_2]^{\frac{1}{2}}$
- C$\frac{-d[NO]}{dt} = k[NO][H_2]^2$
- D$\frac{-d[NO]}{dt} = k[NO][H_2]$
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Similar Questions
At a certain temperature,the half-life periods for the catalytic decomposition of $NH_3$ were found to be as follows:
Pressure $(mm \ Hg)$ $50, 100, 200$ Half-life period $(hrs)$ $3.52, 1.76, 0.88$
What will be the pressure when the half-life period is $2.5 \ hrs$?
| Pressure $(mm \ Hg)$ | $50, 100, 200$ |
| Half-life period $(hrs)$ | $3.52, 1.76, 0.88$ |
What will be the pressure when the half-life period is $2.5 \ hrs$?
Medium
View SolutionRate law for a reaction is $r=k[A]^2[B]$. If rate constant is $6.25 \ mol^{-2} \ dm^6 \ s^{-1}$,what is the rate of reaction when $[A]=1 \ mol \ dm^{-3}$ and $[B]=0.2 \ mol \ dm^{-3}$?
The reaction between $A$ and $B$ is first order with respect to $A$ and zero order with respect to $B$. Fill in the blanks in the following table:
Experiment $[A] / mol \, L^{-1}$ $[B] / mol \, L^{-1}$ Initial rate / $mol \, L^{-1} \, min^{-1}$ $I$ $0.1$ $0.1$ $2.0 \times 10^{-2}$ $II$ $-$ $0.2$ $4.0 \times 10^{-2}$ $III$ $0.4$ $0.4$ $-$ $IV$ $-$ $0.2$ $2.0 \times 10^{-2}$
| Experiment | $[A] / mol \, L^{-1}$ | $[B] / mol \, L^{-1}$ | Initial rate / $mol \, L^{-1} \, min^{-1}$ |
|---|---|---|---|
| $I$ | $0.1$ | $0.1$ | $2.0 \times 10^{-2}$ |
| $II$ | $-$ | $0.2$ | $4.0 \times 10^{-2}$ |
| $III$ | $0.4$ | $0.4$ | $-$ |
| $IV$ | $-$ | $0.2$ | $2.0 \times 10^{-2}$ |
Difficult
View SolutionThe rate law for the reaction $A + B \rightarrow \text{product}$ is $\text{rate} = k[A][B]$. When will the rate of reaction increase by a factor of $2$?
For the reaction $2HI \rightleftharpoons H_2 + I_2$,the rate of the reaction is proportional to $[HI]^2$. This means that the reaction is
Easy
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