The following data were obtained during the first order thermal decomposition of a gas $A$ at constant volume:
$A_{(g)} \rightarrow 2 B_{(g)} + C_{(g)}$

$S.No.$	$Time/s$	$Total Pressure/(atm)$
$1.$	$0$	$0.1$
$2.$	$115$	$0.28$

The rate constant of the reaction is . . . . . . $\times 10^{-2} \ s^{-1}$ (nearest integer).

Assertion : For a first order reaction,$t_{1/2}$ is independent of initial concentration.
Reason : For a first order reaction,rate constant $k \propto [R]$.

Consider the two different first order reactions given below:
$A + B \rightarrow C$ (Reaction $1$)
$P \rightarrow Q$ (Reaction $2$)
The ratio of the half-life of Reaction $1$ : Reaction $2$ is $5 : 2$. If $t_1$ and $t_2$ represent the time taken to complete $2/3$ and $4/5$ of Reaction $1$ and Reaction $2$,respectively,then the value of the ratio $t_1 : t_2$ is $. . . . \times 10^{-1}$ (nearest integer).
[Given: $\log_{10}(3) = 0.477$ and $\log_{10}(5) = 0.699$]

For a first order reaction,the time required for completion of $90 \%$ reaction is '$x$' times the half life of the reaction. The value of '$x$' is $........$. (Given: $\ln 10 = 2.303$ and $\log 2 = 0.3010$)

The rate constant of a first order reaction is $3 \times 10^{-6} \ s^{-1}$. If the initial concentration is $0.10 \ M$,the initial rate of reaction is:

For a first order reaction $A \to B$,the reaction rate at reactant concentration of $0.01 \ M$ is found to be $2.0 \times 10^{-5} \ M \ sec^{-1}$. The half-life period of the reaction is .......... $sec$.