The equilibrium constants for the reactions $X \rightleftharpoons 2Y$ and $Z \rightleftharpoons P + Q$ are $K_{1}$ and $K_{2}$,respectively. If the initial concentrations and the degree of dissociation of $X$ and $Z$ are the same,the ratio $K_{1} / K_{2}$ is

  • A
    $4$
  • B
    $1$
  • C
    $0.5$
  • D
    $2$

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If the pressure in a reaction vessel for the following reaction is increased by decreasing the volume,what will happen to the concentrations of $CO$ and $CO_2$ ?
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In a reaction,$A + B \rightleftharpoons C + D$,$40 \%$ of $B$ has reacted at equilibrium,when $1 \ mol$ of $A$ was heated with $1 \ mol$ of $B$ in a $10 \ L$ closed vessel. The value of $K_C$ is

Thermal decomposition of gaseous $X_2$ to gaseous $X$ at $298 \ K$ takes place according to the following equation :
$X_{2(g)} \rightleftharpoons 2 X_{(g)}$
The standard reaction Gibbs energy,$\Delta_r G^{\circ}$,of this reaction is positive. At the start of the reaction,there is one mole of $X_2$ and no $X$. As the reaction proceeds,the number of moles of $X$ formed is given by $\beta$. Thus,$\beta_{\text{equilibrium}}$ is the number of moles of $X$ formed at equilibrium. The reaction is carried out at a constant total pressure of $2 \ bar$. Consider the gases to behave ideally. (Given : $R=0.083 \ L \ bar \ K^{-1} \ mol^{-1}$)
$(1)$ The equilibrium constant $K_P$ for this reaction at $298 \ K$,in terms of $\beta_{\text{equilibrium}}$,is
$(A)$ $\frac{8 \beta_{\text{equilibrium}}^2}{2-\beta_{\text{equilibrium}}}$ $(B)$ $\frac{8 \beta_{\text{equilibrium}}^2}{4-\beta_{\text{equilibrium}}^2}$ $(C)$ $\frac{4 \beta_{\text{equilibrium}}^2}{2-\beta_{\text{equilibrium}}}$ $(D)$ $\frac{4 \beta_{\text{equilibrium}}^2}{4-\beta_{\text{equilibrium}}^2}$
$(2)$ The $INCORRECT$ statement among the following,for this reaction,is
$(A)$ Decrease in the total pressure will result in formation of more moles of gaseous $X$
$(B)$ At the start of the reaction,dissociation of gaseous $X_2$ takes place spontaneously
$(C)$ $\beta_{\text{equilibrium}}=0.7$
$(D)$ $K_c < 1$

In the reaction $A + 2B \rightleftharpoons 2C$,if $2$ moles of $A$,$3.0$ moles of $B$ and $2.0$ moles of $C$ are placed in a $2.0 \ L$ flask and the equilibrium concentration of $C$ is $0.5 \ mol/L$. The equilibrium constant $K_c$ for the reaction is:

For the reaction $N_2 + O_2 \rightleftharpoons 2NO$,the equilibrium concentrations of $N_2$,$O_2$,and $NO$ are $0.25 \ mol/L$,$0.05 \ mol/L$,and $1.0 \ mol/L$ respectively. What are the initial concentrations of $N_2$ and $O_2$?

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