Thermal decomposition of gaseous $X_2$ to gaseous $X$ at $298 \ K$ takes place according to the following equation :
$X_{2(g)} \rightleftharpoons 2 X_{(g)}$
The standard reaction Gibbs energy,$\Delta_r G^{\circ}$,of this reaction is positive. At the start of the reaction,there is one mole of $X_2$ and no $X$. As the reaction proceeds,the number of moles of $X$ formed is given by $\beta$. Thus,$\beta_{\text{equilibrium}}$ is the number of moles of $X$ formed at equilibrium. The reaction is carried out at a constant total pressure of $2 \ bar$. Consider the gases to behave ideally. (Given : $R=0.083 \ L \ bar \ K^{-1} \ mol^{-1}$)
$(1)$ The equilibrium constant $K_P$ for this reaction at $298 \ K$,in terms of $\beta_{\text{equilibrium}}$,is
$(A)$ $\frac{8 \beta_{\text{equilibrium}}^2}{2-\beta_{\text{equilibrium}}}$ $(B)$ $\frac{8 \beta_{\text{equilibrium}}^2}{4-\beta_{\text{equilibrium}}^2}$ $(C)$ $\frac{4 \beta_{\text{equilibrium}}^2}{2-\beta_{\text{equilibrium}}}$ $(D)$ $\frac{4 \beta_{\text{equilibrium}}^2}{4-\beta_{\text{equilibrium}}^2}$
$(2)$ The $INCORRECT$ statement among the following,for this reaction,is
$(A)$ Decrease in the total pressure will result in formation of more moles of gaseous $X$
$(B)$ At the start of the reaction,dissociation of gaseous $X_2$ takes place spontaneously
$(C)$ $\beta_{\text{equilibrium}}=0.7$
$(D)$ $K_c < 1$

  • A
  • B
  • C
  • D

Explore More

Similar Questions

The equilibrium constants for the following reactions are $K_1$ and $K_2$,respectively.
$2 P_{(g)} + 3 Cl_{2(g)} \rightleftharpoons 2 PCl_{3(g)}$
$PCl_{3(g)} + Cl_{2(g)} \rightleftharpoons PCl_{5(g)}$
Then,the equilibrium constant for the reaction,$2 P_{(g)} + 5 Cl_{2(g)} \rightleftharpoons 2 PCl_{5(g)}$ is

Consider the following chemical equilibrium of the gas phase reaction at a constant temperature: $A_{(g)} \rightleftharpoons B_{(g)} + C_{(g)}$. If $p$ is the total pressure,$K_p$ is the equilibrium constant,and $\alpha$ is the degree of dissociation,then which of the following is true at equilibrium?

For the reaction $N_2 + 3H_2 \rightleftharpoons 2NH_3$,what is the relationship between $\Delta H$ and $\Delta E$?

$2$ moles of $N_2$ are mixed with $6$ moles of $H_2$ in a closed vessel of $1 \ L$ capacity. If $50\%$ of $N_2$ is converted into $NH_3$ at equilibrium,find the value of $K_c$ for the reaction: $N_{2(g)} + 3H_{2(g)} \rightleftharpoons 2NH_{3(g)}$

Dihydrogen gas is obtained from natural gas by partial oxidation with steam as per the following endothermic reaction:
$CH_{4(g)} + H_2O_{(g)} \rightleftharpoons CO_{(g)} + 3H_{2(g)}$
$(a)$ Write an expression for $K_p$ for the above reaction.
$(b)$ How will the values of $K_p$ and the composition of the equilibrium mixture be affected by:
$(i)$ increasing the pressure
$(ii)$ increasing the temperature
$(iii)$ using a catalyst?

Vedclass Products

For Students

Vedclass Test Series

Mock tests in real JEE/NEET style with performance analysis. 5-day free trial.

Start Free Trial
For Teachers

Exam Paper Generator

Generate Set A/B/C/D exam papers from 7.5L+ questions in 2 minutes. 3 chapters free.

Try Free
For Institutes

Online Exam Module

Live online exams with unlimited students, 360° analytics & white-label branding.

See Demo