The equilibrium $2 Cu^{+} \rightleftharpoons Cu + Cu^{2+}$ in aqueous medium at $25^{\circ} C$ shifts towards the left in the presence of
$(A)$ $NO_3^{-}$ $(B)$ $Cl^{-}$ $(C)$ $SCN^{-}$ $(D)$ $CN^{-}$

  • A
    $(B, C, D)$
  • B
    $(A, B, C)$
  • C
    $(A, B, D)$
  • D
    $(A, C, D)$

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Dihydrogen gas is obtained from natural gas by partial oxidation with steam as per the following endothermic reaction:
$CH_{4(g)} + H_2O_{(g)} \rightleftharpoons CO_{(g)} + 3H_{2(g)}$
$(a)$ Write an expression for $K_p$ for the above reaction.
$(b)$ How will the values of $K_p$ and the composition of the equilibrium mixture be affected by:
$(i)$ increasing the pressure
$(ii)$ increasing the temperature
$(iii)$ using a catalyst?

Explain the effect of adding $(i)$ Oxalic acid $(H_2C_2O_4)$,$(ii)$ $HgCl_2$,and $(iii)$ Potassium thiocyanate $(KSCN)$ on the equilibrium reaction: $Fe^{3+}(aq) + SCN^-(aq) \rightleftharpoons [Fe(SCN)]^{2+}(aq)$ (deep red color).

Difficult
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Select the correct statement from the following:

What is the optimum temperature maintained in the Haber process for the production of ammonia (in $K$)?

What happens when an inert gas is added at constant pressure to a reversible decomposition reaction that is in equilibrium?

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