(B) The cell reaction is $Zn(s) + Cu^{2+}(aq) \rightarrow Zn^{2+}(aq) + Cu(s)$.Using the $Nernst$ equation: $E = E^o - \frac{0.0591}{2} \log \frac{[Zn

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(B) The cell reaction is $Zn(s) + Cu^{2+}(aq) \rightarrow Zn^{2+}(aq) + Cu(s)$.Using the $Nernst$ equation: $E = E^o - \frac{0.0591}{2} \log \frac{[Zn^{2+}]}{[Cu^{2+}]}$.For ${E_1}$: $[Zn^{2+}] = 0.01 \ M$ and $[Cu^{2+}] = 1.0 \ M$,so ${E_1} = E^o - \frac{0.0591}{2} \log \frac{0.01}{1} = E^o + 0.0591$.For ${E_2}$: $[Zn^{2+}] = 1.0 \ M$ and $[Cu^{2+}] = 0.01 \ M$,so ${E_2} = E^o - \frac{0.0591}{2} \log \frac{1}{0.01} = E^o - 0.0591$.Therefore,${E_1} > {E_2}$.

Class 12 Chemistry Electrochemistry Nernst equation and ECS

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The $emf$ of a $Daniel$ cell at $298 \ K$ is ${E_1}$ for the cell reaction $Zn|ZnSO_4(0.01 \ M)||CuSO_4(1.0 \ M)|Cu$. When the concentration of $ZnSO_4$ is $1.0 \ M$ and that of $CuSO_4$ is $0.01 \ M$,the $emf$ changes to ${E_2}$. What is the relationship between ${E_1}$ and ${E_2}$?

AIPMT 2003 All AIPMT

A
${E_2} = 0 \neq {E_1}$
B
${E_1} > {E_2}$
C
${E_1} < {E_2}$
D
${E_1} = {E_2}$

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Nernst equation and ECS

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For the cell reaction,$3 Sn^{4+} + 2 Cr \longrightarrow 3 Sn^{2+} + 2 Cr^{3+}$,$E^{\circ}_{cell}$ is $0.89 \ V$. Then $\Delta G^{\circ}$ for the reaction is

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For an electrochemical cell
$Sn_{(s)} | Sn^{2+}(aq, 1 \ M) || Pb^{2+}(aq, 1 \ M) | Pb_{(s)}$
the ratio $\frac{[Sn^{2+}]}{[Pb^{2+}]}$ when this cell attains equilibrium is
(Given $E^{0}_{Sn^{2+}/Sn} = -0.14 \ V$,$E^{0}_{Pb^{2+}/Pb} = -0.13 \ V$,$\frac{2.303 \ RT}{F} = 0.06$)

JEE MAIN 2020

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The $EMF$ of the cell $Cr|Cr^{3+}(0.1 \ M) \| Fe^{2+}(0.01 \ M)|Fe$ is: $(E^{\circ}_{Cr^{3+}|Cr} = -0.75 \ V, E^{\circ}_{Fe^{2+}|Fe} = -0.45 \ V)$ (in $V$)

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Calculate the cell potential for a $Cu$ plate kept in $0.2 \ M$ $CuSO_4$ solution. Given: $E_{Cu^{2+} \mid Cu}^o = 0.34 \ V$. (in $V$)

Medium

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For the cell,$Mn_{(s)}|Mn_{(aq)}^{2+}(0.4\,M)||Sn_{(aq)}^{2+}(0.04\,M)|Sn_{(s)}$,calculate the free energy change $(\Delta G)$ at $298\,K$ in $kJ$.
Given: $E_{Mn^{2+}|Mn}^o = -1.18\,V$; $E_{Sn^{2+}|Sn}^o = -0.14\,V$; $\frac{2.303\,RT}{F} = 0.06$

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The $emf$ of a $Daniel$ cell at $298 \ K$ is ${E_1}$ for the cell reaction $Zn|ZnSO_4(0.01 \ M)||CuSO_4(1.0 \ M)|Cu$. When the concentration of $ZnSO_4$ is $1.0 \ M$ and that of $CuSO_4$ is $0.01 \ M$,the $emf$ changes to ${E_2}$. What is the relationship between ${E_1}$ and ${E_2}$?

Similar Questions

For the cell reaction,$3 Sn^{4+} + 2 Cr \longrightarrow 3 Sn^{2+} + 2 Cr^{3+}$,$E^{\circ}_{cell}$ is $0.89 \ V$. Then $\Delta G^{\circ}$ for the reaction is

For an electrochemical cell$Sn_{(s)} | Sn^{2+}(aq, 1 \ M) || Pb^{2+}(aq, 1 \ M) | Pb_{(s)}$the ratio $\frac{[Sn^{2+}]}{[Pb^{2+}]}$ when this cell attains equilibrium is(Given $E^{0}_{Sn^{2+}/Sn} = -0.14 \ V$,$E^{0}_{Pb^{2+}/Pb} = -0.13 \ V$,$\frac{2.303 \ RT}{F} = 0.06$)

The $EMF$ of the cell $Cr|Cr^{3+}(0.1 \ M) \| Fe^{2+}(0.01 \ M)|Fe$ is: $(E^{\circ}_{Cr^{3+}|Cr} = -0.75 \ V, E^{\circ}_{Fe^{2+}|Fe} = -0.45 \ V)$ (in $V$)

Calculate the cell potential for a $Cu$ plate kept in $0.2 \ M$ $CuSO_4$ solution. Given: $E_{Cu^{2+} \mid Cu}^o = 0.34 \ V$. (in $V$)

For the cell,$Mn_{(s)}|Mn_{(aq)}^{2+}(0.4\,M)||Sn_{(aq)}^{2+}(0.04\,M)|Sn_{(s)}$,calculate the free energy change $(\Delta G)$ at $298\,K$ in $kJ$.Given: $E_{Mn^{2+}|Mn}^o = -1.18\,V$; $E_{Sn^{2+}|Sn}^o = -0.14\,V$; $\frac{2.303\,RT}{F} = 0.06$

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For an electrochemical cell
$Sn_{(s)} | Sn^{2+}(aq, 1 \ M) || Pb^{2+}(aq, 1 \ M) | Pb_{(s)}$
the ratio $\frac{[Sn^{2+}]}{[Pb^{2+}]}$ when this cell attains equilibrium is
(Given $E^{0}_{Sn^{2+}/Sn} = -0.14 \ V$,$E^{0}_{Pb^{2+}/Pb} = -0.13 \ V$,$\frac{2.303 \ RT}{F} = 0.06$)

For the cell,$Mn_{(s)}|Mn_{(aq)}^{2+}(0.4\,M)||Sn_{(aq)}^{2+}(0.04\,M)|Sn_{(s)}$,calculate the free energy change $(\Delta G)$ at $298\,K$ in $kJ$.
Given: $E_{Mn^{2+}|Mn}^o = -1.18\,V$; $E_{Sn^{2+}|Sn}^o = -0.14\,V$; $\frac{2.303\,RT}{F} = 0.06$