Statement $(I)$: Gas thermometers are less sensitive than liquid thermometers.
Statement $(II)$: The ratio of the universal gas constant and Avogadro's number is called Boltzmann's constant.
Statement $(III)$: The density of a given mass of a gas at constant pressure is inversely proportional to its absolute temperature.
The correct option among the following is:

  • A
    Statements $I, II, III$ are true.
  • B
    Statements $I, II$ are true,but statement $III$ is false.
  • C
    Statements $II, III$ are true,but statement $I$ is false.
  • D
    Statements $I, II, III$ are false.

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The left and right compartments of a thermally isolated container of length $L$ are separated by a thermally conducting,movable piston of area $A$. The left and right compartments are filled with $\frac{3}{2}$ and $1$ moles of an ideal gas,respectively. In the left compartment,the piston is attached by a spring with spring constant $k$ and natural length $\frac{2L}{5}$. In thermodynamic equilibrium,the piston is at a distance $\frac{L}{2}$ from the left and right edges of the container as shown in the figure. Under the above conditions,if the pressure in the right compartment is $P = \frac{kL}{A} \alpha$,then the value of $\alpha$ is:

As shown schematically in the figure,two vessels contain water solutions (at temperature $T$) of potassium permanganate $(KMnO_4)$ of different concentrations $n_1$ and $n_2$ $(n_1 > n_2)$ molecules per unit volume with $\Delta n = (n_1 - n_2) \ll n_1$. When they are connected by a tube of small length $\ell$ and cross-sectional area $S$,$KMnO_4$ starts to diffuse from the left to the right vessel through the tube. Consider the collection of molecules to behave as dilute ideal gases and the difference in their partial pressure in the two vessels causing the diffusion. The speed $v$ of the molecules is limited by the viscous force $-\beta v$ on each molecule,where $\beta$ is a constant. Neglecting all terms of the order $(\Delta n)^2$,which of the following is/are correct? ($k_B$ is the Boltzmann constant)
$(A)$ the force causing the molecules to move across the tube is $\Delta n k_B T S$
$(B)$ force balance implies $n_1 \beta v \ell = \Delta n k_B T$
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