Statement-$1$: Few drops of $HNO_3$ are added before proceeding to $III^{rd}$ group.
Statement-$2$: For the oxidation of $Fe^{+2} \rightarrow Fe^{+3}$.

The group reagent for the precipitation of group $II$ basic radicals in qualitative analysis is:

Which ion will form a precipitate with both $HCl$ and $H_2S$?

Choose the correct tests with respective observations.
$(A)$ $CuSO_4$ (acidified with acetic acid) $+$ $K_4[Fe(CN)_6]$ $\rightarrow$ Chocolate brown precipitate.
$(B)$ $FeCl_3 + K_4[Fe(CN)_6]$ $\rightarrow$ Prussian blue precipitate.
$(C)$ $ZnCl_2 + K_4[Fe(CN)_6]$,neutralised with $NH_4OH$ $\rightarrow$ White or bluish white precipitate.
$(D)$ $MgCl_2 + K_4[Fe(CN)_6]$ $\rightarrow$ Blue precipitate.
$(E)$ $BaCl_2 + K_4[Fe(CN)_6]$,neutralised with $NaOH$ $\rightarrow$ White precipitate.
Choose the correct answer from the options given below:

$A$ mixture of two salts is used to prepare a solution $S$,which gives the following results:
White precipitate$(s)$ $\xleftarrow{\text{Dilute } NaOH(aq.) \text{ at Room temperature}}$ $S$ (aq. solution of the salts) $\xrightarrow{\text{Dilute } HCl(aq.) \text{ at Room temperature}}$ White precipitate$(s)$ only
The correct option$(s)$ for the salt mixture is(are):
$A$. $Pb(NO_3)_2$ and $Zn(NO_3)_2$
$B$. $Pb(NO_3)_2$ and $Bi(NO_3)_3$
$C$. $AgNO_3$ and $Bi(NO_3)_3$
$D$. $Pb(NO_3)_2$ and $Hg(NO_3)_2$

Match List-$I$ with List-$II$ :

List-$I$ (Metal Ion)	List-$II$ (Group in Qualitative analysis)
$(a)$ $Mn^{2+}$	$(i)$ Group-$III$
$(b)$ $As^{3+}$	$(ii)$ Group-$IIA$
$(c)$ $Cu^{2+}$	$(iii)$ Group-$IV$
$(d)$ $Al^{3+}$	$(iv)$ Group-$IIB$

Choose the most appropriate answer from the options given below :