Spiegeleisen is an alloy of

Match List-$I$ with List-$II$.

List-$I$ (Industrial process)	List-$II$ (Application)
$(a)$ Haber's process	$(i)$ $HNO_{3}$ synthesis
$(b)$ Ostwald's process	$(ii)$ Aluminium extraction
$(c)$ Contact process	$(iii)$ $NH_{3}$ synthesis
$(d)$ Hall-Heroult process	$(iv)$ $H_{2}SO_{4}$ synthesis

Choose the correct answer from the options given below:

Ellingham diagrams can be drawn for which of the following?

Consider the following metallurgical processes:
$I$. Heating impure metal with $CO$ and distilling the resulting volatile carbonyl (b.p. $43 \ ^oC$) and finally decomposition at $150 \ ^oC - 200 \ ^oC$ to get the pure metal.
$II$. Heating the sulphide ore in air until a part is converted to oxide and then further heating in the absence of air to let the oxide react with unchanged metal sulphide.
$III$. Electrolysis of the molten electrolyte containing approximately equal amounts of the metal chloride and $NaCl$ to obtain the metal.
The processes used for obtaining magnesium,nickel and copper are respectively:

In aluminium extraction by the Bayer process,alumina is extracted from bauxite by sodium hydroxide at high temperature and pressure: $Al_2O_{3(s)} + 2 OH^-_{(aq)} + 3 H_2O_{(l)} \rightarrow 2 [Al(OH)_4]^-_{(aq)}$. Solid impurities such as $Fe_2O_3$ and $SiO_2$ are removed and then $[Al(OH)_4]^-$ is reprecipitated: $2 [Al(OH)_4]^-_{(aq)} \rightarrow Al_2O_3 \cdot 3 H_2O_{(s)} + 2 OH^-_{(aq)}$. In the industrial world:

In the Ellingham diagram,the plot is drawn between: