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The smelting of iron in the blast furnace involves all the following processes except:

Match the conversions in Column-$I$ with the type$(s)$ of reaction$(s)$ given in Column-$II$.
Column-$I$ Column-$II$
$A$. $PbS \rightarrow PbO$ $p$. roasting
$B$. $CaCO_3 \rightarrow CaO$ $q$. calcination
$C$. $ZnS \rightarrow Zn$ $r$. Carbon reduction
$D$. $Cu_2S \rightarrow Cu$ $s$. self reduction

Match List-$I$ with List-$II$:
List-$I$ (Property) List-$II$ (Element/compound)
$I$. Explosive $A$. $Cu$
$II$. Self-reduction $B$. $Fe_3O_4$
$III$. Magnetic material $C$. $Cu(CH_3COO)_2 \cdot Cu(OH)_2$
$IV$. Verdigris $D$. $Pb(NO_3)_2$

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Concentrated sodium hydroxide can separate a mixture of

Identify the reaction,which is not related to the extraction of copper.

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