Rank the transition states that occur during the following reaction steps in order of increasing stability (least $\to$ most stable):
$1. CH_3-OH_2^+ \to CH_3^+ + H_2O$
$2. (CH_3)_3C-OH_2^+ \to (CH_3)_3C^+ + H_2O$
$3. (CH_3)_2CH-OH_2^+ \to (CH_3)_2CH^+ + H_2O$

  • A
    $1 < 2 < 3$
  • B
    $2 < 3 < 1$
  • C
    $1 < 3 < 2$
  • D
    $2 < 1 < 3$

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In the following carbocation,the $H$ or $CH_3$ group that is most likely to migrate to the positively charged carbon is:

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$III: ^+CH_2-CH_3$

Based upon an understanding of product stability,predict the product formed when the following dianion reacts with one equivalent of acid $(H^+)$.

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