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What is the main reason for the fact that carboxylic acids can undergo ionization?

Among the following compounds,the most acidic is

$EtO-CO-OEt \xrightarrow[(2) H_3O^{+}]{(1) CH_3MgBr \text{ (excess)}} (A)$,Product $(A)$ is:

Which of the following carboxylic acids has the least $pK_{a}$ value?

Which of the following is the correct order of relative acidity for the given acids?

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