Plotting $1 / \Lambda_{m}$ against $c \Lambda_{m}$ for aqueous solutions of a monobasic weak acid $(HX)$ resulted in a straight line with $y$-axis intercept of $P$ and slope of $S$. The ratio $P / S$ is
$[\Lambda_{m} =$ molar conductivity
$\Lambda_{m}^{\circ} =$ limiting molar conductivity
$c =$ molar concentration
$K_{a} =$ dissociation constant of $HX$ ]
$[\Lambda_{m} =$ molar conductivity
$\Lambda_{m}^{\circ} =$ limiting molar conductivity
$c =$ molar concentration
$K_{a} =$ dissociation constant of $HX$ ]
- A$K_{a} \Lambda_{m}^{\circ}$
- B$K_{a} \Lambda_{m}^{\circ} / 2$
- C$2 K_{a} \Lambda_{m}^{\circ}$
- D$1 / (K_{a} \Lambda_{m}^{\circ})$
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$(A)$ At $298 \ K$,the potential of a hydrogen electrode placed in a solution of $pH = 10$ is $-0.59 \ V$.
$(B)$ The limiting molar conductivity of $Ca^{2+}$ and $Cl^{-}$ are $119$ and $76 \ S \ cm^2 \ mol^{-1}$ respectively. The limiting molar conductivity of $CaCl_2$ is $195 \ S \ cm^2 \ mol^{-1}$.
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