Identify the correct statements from the following:
$(A)$ At $298 \ K$,the potential of a hydrogen electrode placed in a solution of $pH = 10$ is $-0.59 \ V$.
$(B)$ The limiting molar conductivity of $Ca^{2+}$ and $Cl^{-}$ are $119$ and $76 \ S \ cm^2 \ mol^{-1}$ respectively. The limiting molar conductivity of $CaCl_2$ is $195 \ S \ cm^2 \ mol^{-1}$.
$(C)$ The correct relationship between $K_{c}$ and $E_{cell}^{0}$ is $E_{cell}^{0} = \frac{2.303 RT}{nF} \log K_{c}$.

  • A
    $A, B, C$
  • B
    $A, B$ only
  • C
    $A, C$ only
  • D
    $B, C$ only

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The molar conductivity of $0.025 \ mol \ L^{-1}$ methanoic acid is $46.1 \ S \ cm^2 \ mol^{-1}$. Calculate its degree of dissociation and dissociation constant. Given $\lambda^o(H^{+}) = 349.6 \ S \ cm^2 \ mol^{-1}$ and $\lambda^o(HCOO^{-}) = 54.6 \ S \ cm^2 \ mol^{-1}$.

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Consider the following redox reaction :
$MnO_4^{-} + H^{+} + H_2C_2O_4 \rightleftharpoons Mn^{2+} + H_2O + CO_2$
The standard reduction potentials are given as below $(E_{red}^{\circ})$ :
$E_{MnO_4^{-} / Mn^{2+}}^{\circ} = +1.51 \ V$
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If the equilibrium constant of the above reaction is given as $K_{eq} = 10^x$,then the value of $x = $ . . . . . . (nearest integer).

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