Pick the correct statement.

In the depression of freezing point experiment,it is found that the:

Solid Lead nitrate is dissolved in $1 \, L$ of water. The solution was found to boil at $100.15^{\circ}C$. When $0.2 \, mol$ of $NaCl$ is added to the resulting solution,it was observed that the solution froze at $-0.8^{\circ}C$. The solubility product of $PbCl_2$ formed is $........... \times 10^{-6}$ at $298 \, K$. (Nearest integer) Given: $K_b = 0.5 \, K \, kg \, mol^{-1}$ and $K_f = 1.8 \, K \, kg \, mol^{-1}$. Assume molality to be equal to molarity in all cases.

Give examples of ideal solutions and azeotropes.

The specific heat of a certain substance is $0.86 \,J \,g^{-1} \,K^{-1}$. Assuming ideal solution behaviour,the energy required (in $J$) to heat $10 \,g$ of $1 \,molal$ of its aqueous solution from $300 \,K$ to $310 \,K$ is closest to $.... \,J$
[Given: Molar mass of the substance $= 58 \,g \,mol^{-1}$; specific heat of water $= 4.2 \,J \,g^{-1} \,K^{-1}$]

Match the following.

List-$I$	List-$II$
$(A)$ Azeotrope	$(I)$ $\Delta T_b = i K_b m$
$(B)$ Henry's law	$(II)$ $p = K_H x$
$(C)$ Cryoscopic constant	$(III)$ $\Delta T_f / m$
$(D)$ Van't Hoff factor	$(IV)$ Deviation from Raoult's law
	$(V)$ $\pi = CRT$

The correct answer is