Permanganate ion reacts with bromide ion in basic medium to give manganese dioxide and bromate ion. Write the balanced ionic equation for the reaction.

Vedclass pdf generator app on play store
Vedclass iOS app on app store
(N/A) Step $1$: The skeletal ionic equation is: $MnO_4^{-}{(aq)} + Br^{-}{(aq)} \rightarrow MnO_{2(s)} + BrO_3^{-}{(aq)}$
Step $2$: Assign oxidation numbers for $Mn$ and $Br$: $\mathop{Mn}\limits^{+7}O_4^{-}{(aq)} + \mathop{Br^{-}}\limits^{-1}{(aq)}$ $\rightarrow \mathop{Mn}\limits^{+4}O_{2(s)} + \mathop{Br}\limits^{+5}O_3^{-}{(aq)}$. This indicates that permanganate ion is the oxidant and bromide ion is the reductant.
Step $3$: Calculate the increase and decrease of oxidation number,and make the increase equal to the decrease: $2MnO_4^{-}{(aq)} + Br^{-}{(aq)} \rightarrow 2MnO_{2(s)} + BrO_3^{-}{(aq)}$.
Step $4$: As the reaction occurs in the basic medium,and the ionic charges are not equal on both sides,add $2OH^{-}$ ions on the right to make ionic charges equal: $2MnO_4^{-}{(aq)} + Br^{-}{(aq)} \rightarrow 2MnO_{2(s)} + BrO_3^{-}{(aq)} + 2OH^{-}{(aq)}$.
Step $5$: Finally,count the hydrogen atoms and add appropriate number of water molecules (i.e.,one $H_2O$ molecule) on the left side to achieve balanced redox change: $2MnO_4^{-}{(aq)} + Br^{-}{(aq)} + H_2O_{(l)} \rightarrow 2MnO_{2(s)} + BrO_3^{-}{(aq)} + 2OH^{-}{(aq)}$.

Explore More

Similar Questions

Molecular weight of $Cu_2S$ is $M$. In the following reaction its equivalent weight is $M / x$. What is $x$?
$Cu_2S + MnO_4^{-} \rightarrow Cu^{2+} + Mn^{2+} + SO_2$

Aqueous solutions of $Na_2S_2O_3$ on reaction with $Cl_2$ gives

In the redox reaction
$x \ MnO + y \ PbO_2 + z \ HNO_3 \to a \ HMnO_4 + b \ Pb(NO_3)_2 + c \ H_2O$
Find the values of $x, y, z$.

Assign $A, B, C, D$ from the given type of reaction.
$Mg_{(s)} + 2H_2O_{(l)} \xrightarrow{\text{Warm}} Mg(OH)_{2(aq)} + H_{2(g)} \uparrow$

Assign $A, B, C, D$ from given type of reaction.
$CuSO_4(aq.) + Zn(s) \longrightarrow ZnSO_4(aq.) + Cu(s)$

Difficult
View Solution

Vedclass Products

For Students

Vedclass Test Series

Mock tests in real JEE/NEET style with performance analysis. 5-day free trial.

Start Free Trial
For Teachers

Exam Paper Generator

Generate Set A/B/C/D exam papers from 7.5L+ questions in 2 minutes. 3 chapters free.

Try Free
For Institutes

Online Exam Module

Live online exams with unlimited students, 360° analytics & white-label branding.

See Demo