One half cell in a voltaic cell is constructed by dipping a silver rod in an $AgNO_3$ solution of unknown concentration,and the other half cell is a $Zn$ rod dipped in a $1 \text{ M}$ solution of $ZnSO_4$. $A$ voltage of $1.60 \text{ V}$ is measured at $298 \text{ K}$ for this cell. What is the concentration of $Ag^+$ ions in terms of $\log x$ (where $x = [Ag^+]$)? Given: $E^\ominus_{Zn^{2+}/Zn} = -0.76 \text{ V}$,$E^\ominus_{Ag^+/Ag} = +0.80 \text{ V}$,and $\frac{2.303RT}{F} = 0.059 \text{ V}$.

  • A
    $\frac{2}{3.9}$
  • B
    $\frac{4}{5.9}$
  • C
    $\frac{2.9}{2}$
  • D
    $\frac{5.9}{4}$

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Similar Questions

For the cell reaction with the indicated concentrations
$Al_{(s)} + 3Ag^{+}_{(aq)} \, (0.10 \, M) \to Al^{3+}_{(aq)} \, (0.30 \, M) + 3Ag_{(s)}$,
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Given: $\frac{2.303 \, RT}{F} = 0.06 \, V ; \, \log \, 3 = 0.48$

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If the $E^{\circ}_{cell}$ for a given reaction has a negative value,which of the following gives the correct relationships for the values of $\Delta G^{\circ}$ and $K_{eq}$ ?

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