Mohr salt is prepared from an equimolar solution of:

  • A
    $FeSO_4 \cdot 7 H_2O$ and $K_2SO_4$
  • B
    $FeSO_4 \cdot 7 H_2O$ and $(NH_4)_2SO_4$
  • C
    $CuSO_4 \cdot 5 H_2O$ and $K_2SO_4$
  • D
    $CuSO_4 \cdot 5 H_2O$ and $(NH_4)_2SO_4$

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On treatment of $10 \ mL$ of $1 \ M$ solution of the complex $CrCl_3 \cdot 6H_2O$ with excess of $AgNO_3$,$4.305 \ g$ of $AgCl$ was obtained. The complex is

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Identify the total number of complexes having bidentate ligands in them from the following list of complexes:
$a$) Tetracyanonickelate$(II)$ ion
$b$) Trioxalatocobaltate$(III)$ ion
$c$) Sodium hexafluoroaluminate$(III)$
$d$) bis(ethylenediamine)dithiocyanatoplatinum$(IV)$

The secondary valences (coordination numbers) of the following complexes based on their reactions with excess $AgNO_3$ are:
Formula of the complexesMoles of $AgCl$ precipitated per mole of complex
$(I) \ CoCl_3 \cdot 6 H_2O$$3$
$(II) \ NiCl_3 \cdot 6 H_2O$$2$
$(III) \ Co(SO_4)Br \cdot 5 NH_3$$1$

Find the secondary valences for $(I), (II),$ and $(III)$ respectively.

Number of ions present in $K_4[Fe(CN)_6]$

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