What is the minimum energy required for the homolytic bond fission of the $C-H$ bond in the following molecule?

Rank the transition states that occur during the following reaction steps in order of increasing stability (least $\to$ most stable):
$1.$ $CH_3-O^+H_2 \to CH_3^+ + H_2O$
$2.$ $(CH_3)_3C-O^+H_2 \to (CH_3)_3C^+ + H_2O$
$3.$ $(CH_3)_2CH-O^+H_2 \to (CH_3)_2CH^+ + H_2O$

Which of the following is the least stable carbocation?

Using curved-arrow notation,show the formation of reactive intermediates when the following covalent bonds undergo heterolytic cleavage:
$(a)$ $CH_{3}-SCH_{3}$
$(b)$ $CH_{3}-CN$
$(c)$ $CH_{3}-Cu$

$2-$chloropentane on halogenation with chlorine gives $2,3-$dichloropentane. What will be the structure of the free radical species formed in the reaction?

State whether the following statements are True or False:
$(i)$ $CH_3-CH_2^+$ is more stable than $CH_3^+$
$(ii)$ $CH_3-CH_2^+$ is less stable than $CH_3^+$
$(iii)$ $(CH_3)_3C^+$ is less stable than $CH_3^+$
$(iv)$ $(CH_3)_3C^+$ is more stable than $CH_3^+$