Mechanism of a hypothetical reaction
$X_2 + Y_2 \rightarrow 2XY,$ is given below :
$(i)\,\, X_2 \rightarrow X + X\, (fast)$
$(ii)\,\,X + Y_2 \rightleftharpoons XY + Y\, (slow)$
$(iii)\,\,X + Y \rightarrow XY\, (fast)$
The overall order of the reaction will be
$2$
$0$
$1.5$
$1$
The reaction between $A$ and $B$ is first order with respect to $A$ and zero order with respect to $B$. Fill in the blanks in the following table:
Experiment | $[ A ] / mol\, ^{-1}$ | $[ B ] / mol\, ^{-1}$ | Initial rate $/$ $mol$ $L^{-1}$ $min$ $^{-1}$ |
$I$ | $0.1$ | $0.1$ | $2.0 \times 10^{-2}$ |
$II$ | - | $0.2$ | $4.0 \times 10^{-2}$ |
$III$ | $0.4$ | $0.4$ | - |
$IV$ | - | $0.2$ | $2.0 \times 10^{-2}$ |
The rate of certain reaction depends on concentration according to the equation $\frac{{ - dc}}{{dt}} = \frac{{{K_1}C}}{{1 + {K_2}C}},$ what is the order, when concentration $(c)$ is very-very high
The mechanism for the reaction is given below $2P + Q \to S + T$ $P + Q \to R + S$(slow)$P + R \to T$ (fast)The rate law expression for the reaction is
The rate of disappearance of $S{O_2}$ in the reaction $2S{O_2} + {O_2} \to 2S{O_3}$ is $1.28 \times {10^{ - 3}}g/sec$ then the rate of formation of $S{O_3}$ is
For the reaction between $A$ and $B$ , the initial rate of reaction $(r_0)$ was measured for different initial concentration of $A$ and $B$ as given below Order of the reaction with respect to $A$ and $B$ respectively, is $\sqrt 2 = 1.4 ,\,\sqrt 3 \times 10^{-4}$
$A/mol\,L^{-1}$ | $0.2$ | $0.2$ | $0.4$ |
$B/mol\,L^{-1}$ | $0.3$ | $0.1$ | $0.05$ |
$r_0/mol^{-1}s^{-1}$ | $5.0\times 10^{-5}$ | $5.0\times 10^{-5}$ | $1.4\times 10^{-4}$ |