In which of the following reactions does the addition of $H_2O$ take place according to Markovnikov's rule but without rearrangement?

  • A
    $CH_3-CH(CH_3)-CH=CH_2 \xrightarrow{H^{+}/H_2O} \text{product}$
  • B
    $CH_3-C(Ph)(CH_3)-CH=CH_2 \xrightarrow[2. NaBH_4]{1. Hg(OAc)_2/H_2O} \text{product}$
  • C
    $1-$methylcyclopentene $\xrightarrow[2. H_2O_2/OH^{-}]{1. B_2H_6} \text{product}$
  • D
    Allylbenzene $\xrightarrow{Dil. H_2SO_4} \text{product}$

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Show how you would synthesize the following alcohols from appropriate alkenes:
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$(ii)$ $3$-methylhexan-$3$-ol
$(iii)$ pentan-$2$-ol
$(iv)$ $2$-cyclohexylbutan-$2$-ol

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Explain the methods of preparing alcohols from carbonyl compounds using Grignard reagents.

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What are $X$ and $Y$ in the following reactions?
$CH_2O \xrightarrow[(ii) H_3O^+]{(i) X} CH_3(CH_2)_2CH_2OH$
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$(a)$ Catalytic reduction of butanal.
$(b)$ Hydration of propene in the presence of dilute sulphuric acid.
$(c)$ Reaction of propanone with methylmagnesium bromide followed by hydrolysis.

In order to prepare $1$-chloropropane,which of the following reactants can be employed?

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