In which of the following processes does entropy increase?

One mole of an ideal gas is allowed to expand reversibly and adiabatically from a temperature of $27\,^oC$. If the work done during the process is $3\,kJ$,the final temperature will be equal to $(C_v = 20\,J\,K^{-1} \, mol^{-1})$

$A$ steel steam boiler has a mass of $900 \, kg$ and contains $400 \, kg$ of water. If the boiler and water receive only $70 \%$ of the heat supplied,how much heat in $kcal$ is required to raise the temperature of the boiler and water from $10 \, ^oC$ to $100 \, ^oC$? (Specific heat of steel = $0.11 \, kcal/kg \cdot K$,Specific heat of water = $1.0 \, kcal/kg \cdot K$)

Which of the following relations is correct?

Which graph represents an exothermic reaction?

The enthalpy of dilution of $4 \ M \ HCl$ to $2 \ M \ HCl$ is $-2.5 \ kJ/mol$. Find the enthalpy change when $500 \ mL$ of $4 \ M \ HCl$ is diluted to $2 \ M \ HCl$ (in $kJ$).