The enthalpy of dilution of $4 \ M \ HCl$ to $2 \ M \ HCl$ is $-2.5 \ kJ/mol$. Find the enthalpy change when $500 \ mL$ of $4 \ M \ HCl$ is diluted to $2 \ M \ HCl$ (in $kJ$).

Match the following items in List-$I$ with their corresponding expressions in List-$II$.

List-$I$	List-$II$
$A$. At constant volume the change in internal energy of a system	$I$. $W = -2.303 nRT \log \frac{V_f}{V_i}$
$B$. Isothermal irreversible change	$II$. $W_{adiabatic} = \Delta U$
$C$. Isothermal reversible change	$III$. $q_V = \Delta U$
$D$. Adiabatic change	$IV$. $W = -p_{ex} (V_f - V_i)$
	$V$. $\Delta U = \Delta H - \Delta nRT$

The enthalpy of sublimation of $I_{2(s)}$ is $57.3 \, kJ \, mol^{-1}$ and the enthalpy of fusion is $15.5 \, kJ \, mol^{-1}$. The enthalpy of vaporization of $I_2$ is ..................... $kJ \, mol^{-1}$. (in $.8$)

$9.0 \ g$ of $H_2O$ is vaporised at $100 \ ^oC$ and $1 \ atm$ pressure. If the latent heat of vaporisation of water is $x \ J/g$,then $\Delta S$ is given by

State $1 \longleftarrow$ State $2 \longleftarrow$ State $3$
$\left(\begin{array}{c} T=300 \ K \\ P=15 \ bar \\ 1 \ mole \end{array}\right) \left(\begin{array}{c} T=300 \ K \\ P=10 \ bar \\ 1 \ mole \end{array}\right) \left(\begin{array}{c} T=300 \ K \\ P=5 \ bar \\ 1 \ mole \end{array}\right)$
The above shows a cyclic process. Calculate the total work done during one complete cycle. (Assume a single step to reach the next state).

One gram sample of $NH_4NO_3$ is decomposed in a bomb calorimeter. The temperature of the calorimeter increases by $6.12 \ K$. The heat capacity of the system is $1.23 \ kJ/K$. What is the molar heat of decomposition for $NH_4NO_3$ in $kJ/mol$?