In the following reaction,what is the value of equilibrium constant?
$Cu_{(s)} + 2 Ag_{(aq)}^{+} \rightarrow Cu_{(aq)}^{2+} + 2 Ag_{(s)}$
$E_{cell}^0 = 0.46 \ V$

  • A
    $3.92 \times 10^{10}$
  • B
    $3.92 \times 10^{15}$
  • C
    $39.2 \times 10^{15}$
  • D
    $3.92 \times 10^{14}$

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Write the Nernst equation for the $E_{cell}$ reaction in the Daniell cell. How will the $E_{cell}$ be affected when the concentration of $Zn^{2+}$ ions is increased?

$Cu_{(s)} | Cu^{+2}(aq, 10^{-3} M) || Ag^{+}(aq, 10^{-5} M) | Ag_{(s)}$
If $E^{o}_{Cu^{+2}/Cu} = +0.34 \ V$
$E^{o}_{Ag^{+}/Ag} = +0.80 \ V$
$E_{cell}$ will be

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For the cell $Zn_{(s)} | Zn^{2+}_{(1\,M)} || Cu^{2+}_{(1\,M)} | Cu_{(s)}$,the $E^o_{cell} = 1.10 \, V$. When the cell is fully discharged at $298 \, K$,the ratio of the concentrations $[Zn^{2+}] / [Cu^{2+}]$ is:

In the electrochemical cell $:$
$Zn \,|\,ZnSO_4\,(0.01\,M)\,||\,CuSO_4\,(1.0\,M)\,|\,Cu$
the $emf$ of this Daniell cell is $E_1.$ When the concentration of $ZnSO_4$ is changed to $1.0\,M$ and that of $CuSO_4$ changed to $0.01\,M,$ the $emf$ changes to $E_2.$ From the followings,which one is the relationship between $E_1$ and $E_2$ $?$ (Given,$RT/F = 0.059$)

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