In Kjeldahl's method for the estimation of nitrogen,the formula used is

In Dumas method,$0.3 \ g$ of an organic compound gave $45 \ mL$ of nitrogen at $STP$. The percentage of nitrogen is

In the Dumas method for the estimation of nitrogen,$0.388 \ g$ of an organic compound yielded $1.31 \ mL$ of $N_2$ gas collected at $293 \ K$ temperature and $746 \ mm$ pressure. Calculate the percentage of nitrogen in the compound. (Aqueous tension at $293 \ K = 6 \ mm$). (in $\%$)

Match column $-I$ and column $-II$ with the correct relation:

Column $-I$	Column $-II$
$(i)$ Dumas method	$(a)$ Absorption of $NH_3$ in $H_2SO_4$
$(ii)$ Kjeldahl's method	$(b)$ $BaCl_2$ by added $BaSO_4$
$(iii)$ Carius method	$(c)$ Mixture of Magnesia
$(iv)$ Estimation of phosphorus	$(d)$ $N_2$

In the Carius method,$0.2425 \ g$ of an organic compound gave $0.5253 \ g$ of silver chloride. The percentage of chlorine in the organic compound is: (in $\%$)

In phosphorus estimation,$0.31 \ g$ of an organic compound gave $0.444 \ g$ of magnesium pyrophosphate (molar mass $= 222 \ g \ mol^{-1}$). The percentage of phosphorus in the compound is