If the $O.P.$ (Osmotic Pressure) of $1 \ M$ solutions of the following compounds in water can be measured,which one will show the maximum $O.P.$?

$A$ solution containing $0.85 \ g$ of $ZnCl_2$ in $125.0 \ g$ of water freezes at $-0.23 \ ^\circ C$. The apparent degree of dissociation of the salt is ($K_f$ for water $= 1.86 \ K \ kg \ mol^{-1}$,atomic mass: $Zn = 65.3$ and $Cl = 35.5$)

Calculate the depression in the freezing point of water when $10 \ g$ of $CH_3CH_2CHClCOOH$ is added to $250 \ g$ of water. $K_a = 1.4 \times 10^{-3}$,$K_f = 1.86 \ K \ kg \ mol^{-1}$

Which of the following $0.1 \ M$ solutions will exhibit the minimum freezing point?

Which of the following aqueous solutions having same molality exhibits maximum boiling point elevation? (Assume complete dissociation)

For a $0.2 \ m$ aqueous solution of a weak acid $HX$,the degree of ionization is $0.3$. If $K_f$ for water is $1.85 \ K \ kg \ mol^{-1}$,the freezing point of the solution will be close to .......... $^oC$.