Identify the product formed from chlorobenzen | vedclass

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(C) Chlorobenzene undergoes electrophilic aromatic substitution (nitration) when treated with a mixture of conc. $HNO_3$ and conc. $H_2SO_4$.Because t

Vedclass · Accepted Answer

Mixture of $1-$chloro$-4-$nitrobenzene and $1-$chloro$-2-$nitrobenzene

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(C) Chlorobenzene undergoes electrophilic aromatic substitution (nitration) when treated with a mixture of conc. $HNO_3$ and conc. $H_2SO_4$.Because the chlorine atom is ortho/para-directing due to the resonance effect,the nitration occurs at both the $ortho$ and $para$ positions.Therefore,the reaction yields a mixture of $1-$chloro$-2-$nitrobenzene ($ortho$-isomer) and $1-$chloro$-4-$nitrobenzene ($para$-isomer).

Identify the product formed from chlorobenzene on heating with conc. $HNO_3$ in the presence of conc. $H_2SO_4$.

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